Where the critical angle comes from
Leaving glass for air, the ray bends away from the normal, so the angle in the air is always the larger. Increase the angle in the glass and the angle in the air reaches 90° first: the refracted ray skims the surface. Put \(\theta_{2} = 90^{\circ}\) in Snell’s law, \(n_{1} \sin \theta_\mathrm{c} = n_{2} \sin 90^{\circ}\), and \(\sin \theta_\mathrm{c} = \frac{n_{2}}{n_{1}}\). Beyond that angle, Snell’s law would need a sine greater than 1, which is impossible: there is no refracted ray.
“Total” means total
Below the critical angle some light is reflected and some escapes. Beyond it, all of the light is reflected. No mirror does as well, which is why prisms, not mirrors, turn the light in binoculars.
Optical fibers
A thin glass fiber is coated with glass of slightly lower refractive index. Light sent in at one end meets the wall at a large angle, beyond the critical angle, and is totally reflected again and again along the whole length. Fibers carry telephone and internet signals under the oceans, and let surgeons see inside the body.